Mark Zuckerberg – Priscilla Chan
No one can accuse Priscilla Chan of being a gold digger. She had been dating Mark Zuckerberg way before the big Facebook boom. If anything, as a med student, she was the more likely one to make more money if he hadn’t invented the yardstick for social media. The couple met at a frat party, and after years of dating, got married in an intimate backyard wedding at Zuckerberg’s house. Despite her husband’s billions, Chan also still practiced as a pediatrician but has since put it on the backburner to do philanthropic work with the Chan Zuckerberg Initiative.